UNDECYLENIC ALCOHOL |
PRODUCT
IDENTIFICATION
|
CAS
NO. |
112-43-6 |
|
EINECS NO. |
203-971-0 |
FORMULA |
C11H22O |
MOL
WT. |
170.29 |
H.S.
CODE |
2905.19 |
TOXICITY
|
|
SYNONYMS |
1-Undecen-11-ol; 10-Undecenol;
10-Undecylen-1-ol; |
omega-Undecenyl alcohol; 11-Hydroxy-1-undecene; omega-Undecylenyl alcohol; Undecylenyl
alcohol; 10-Undecene-1-ol; |
SMILES
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CLASSIFICATION
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PHYSICAL AND CHEMICAL PROPERTIES
|
PHYSICAL
STATE |
clear
liquid |
MELTING POINT |
|
BOILING
POINT |
132 - 133 at
15 hPa |
SPECIFIC GRAVITY |
0.84
- 0.85 |
SOLUBILITY
IN WATER |
|
pH |
|
VAPOR DENSITY |
|
AUTOIGNITION
|
|
NFPA
RATINGS
|
Health: 1; Flammability: 3; Reactivity: |
REFRACTIVE
INDEX
|
1.448 |
FLASH
POINT |
|
STABILITY |
Stable under ordinary
conditions |
APPLICATIONS
|
Undecylenic
Acid is an unsaturated
carboxylic acid. The molecules of most natural fatty
acids have an even number of carbon chains due to the linkage together by ester
units. Analogous compounds of odd numbers carbon chain fatty acids are
supplemented synthetically. Pelargonic acid, C-9 odd numbers carbon chain fatty
acid, is relatively high cost fatty acid. Pelargonic acid can be prepared by ozonolysis which uses
ozone is to cleave the alkene bonds. Eexample of ozonolysis in commerce is the
production of odd carbon number carboxylic acids such as azelaic acid and
pelargonic acid and simple carboxylic acids such as formic acid and oxalic acid.
When ricinoleic acid, an unsaturated fatty acid containing one
-OH group, derived from castor oil, is pyrolyzed by
heating
in the absence of air, it breaks down to give undecylenic
acid and n-heptaldehyde. This
product has the bifunctionality, odd carbon number and the
position of its unsaturated solid bond at the end
of the chain, makes it a versatile tool for chemical
synthesis. It's
anti-fungal
properties are useful in cosmetics and pharmaceuticals. Undecylenic
Acid
and its aldehyde are used to formulate perfumes. Undecylenic acid and
its zinc salt are used for the treatment and prevention of superficial fungus infections of the skin,
primarily tinea pedis as well as relieves itching, burning and
irritation.
Undecylenic Alcohol
is one of common ingredient in flavor
and fragrance. Odor description: floral, ozone, waxy.
|
SALES
SPECIFICATION |
APPEARANCE
|
clear
liquid |
ASSAY |
98.0%
min |
MOISTURE |
0.3%
max
|
TRANSPORTATION |
PACKING |
170kgs
in drum |
HAZARD CLASS |
|
UN
NO. |
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GENERAL
DESCRIPTION OF FATTY ALCOHOL
|
Fatty alcohols, derived from natural fats and oils, are high molecular straight
chain primary alcohols. They include lauryl (C12), MyrIstyl (C14), Cetyl ( or
palmityl: C16), stearyl (C18), Oleyl (C18, unsaturated), and Linoleyl (C18,
polyunsaturated) alcohols. There are synthetic fatty alcohols equivalent
physically and chemically to natural alcohols obtained from oleochemical sources
such as coconut and palm kernel oil. Fatty alcohols are emulsifiers and
emollients to make skin smoother and prevent moisture loss. Identical fatty
esters are used to improve rub-out of formulas and to control viscosity and
dispersion characteristics in cosmetics, personal care products and
pharmaceutical ingredients. As chemical intermediates, the primary use of fatty
alcohols are as raw material for the production of fatty sulfate salts and
alcohol ethoxylates for foaming and cleaning purposes in the field of detergent
industry. Chemical reactions of primary alcohols include esterifications,
ethoxylation, sulfation, oxidation and many other reactions. Their derivatives
and end use applications include;
- Nonionic surfactants (Ethoxylates and
propoxylates)
- Anionic surfactants (Alkyl sulfates and alkyl ethoxy
sulfates)
- Chemical intermediates and polymerization modifiers (Alkyl
halides, Alkyl mercaptans)
- Quaternary ammonium compounds for detergent
sanitisers, softner for
textiles, phase
transfer catalyst and
biocides
- Antioxidants for plastics (Alkyl thiopropionates and alkyl
phosphites)
- Lubricant additives (Metallic and thio alkylphosphates)
- Flavor
and Fragrance (Aldehydes and ketones)
- PVC plasticizers (Dialkyl Phthalates,
adipates and trimellitates)
- Coatings and inks (acrylate and methacrylate
esters)
- Water treatment (acrylate and methacrylate esters)
Large
amount of fatty alcohols are used as special solvents, fillers in plasticizer
and insulating materials for the building industry. Fatty alcohols are used as
ingredients in the industries of agricultural, foodstuff, metal processing,
cosmetics, lube additive, pharmaceutical, rubber, textile, perfume and
flavouring as well as synthetic detergent.
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